Science Quiz / Palladium coupling reactions

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Can you name the Palladium coupling reactions?

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substrates/productsnameextra hints
alkenes and aryl halides, gives styrenes and stilbenes-
aryl halides and boronic acids, gives poly-olefins, styrenes, and substituted biphenyls-
organohalides and organotin compounds, gives poly-olefins, styrenes, and substituted biphenyls-
organohalides and organosilicon compounds, gives poly-olefins, styrenes, and substituted biphenylsusually requires activation of the organosilane with fluorides
aryl halides and alkynes, gives access to substituted alkynesuses copper(I) iodide as a co-catalyst
organohalide and an organozinc compound, gives poly-olefins, styrenes, and substituted biphenyls-
Thioester and an organozinc halide, gives Ketones-
aryl halide with an amine, gives aromatic amines-
alkyl or aryl Grignard reagent and an aryl or vinyl halocarbon works also well with nickel
thioesters and a boronic acids, gives ketonesrequires a copper co-catalyst

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