Entertainment Quiz / Priyanka Chopra and Demi Lovato separation

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Can you name the celebrities that make up the romantic connections between Priyanka Chopra and Demi Lovato? (2 clues here)

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1st half of clue
relationship from 2009 to 2011
Separated in Oct 2007 after 4 years
Rumored to had hooked up with....
Were married for 12 years with
Rumored to hook up in 2004
Had encounter in July 2012 with
Divorced on October 18th 2000
Rumored to hooked up in 2005
2nd half of clue

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