Ionic Structures

Can you name the ionic structures from their packing and hole filling?

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Packing and hole fillingIonic StructureKey Example & Cation:Anion coordination
Primitive cubic arrangement of anion with cation in centre
CCP anion, all octahedral holes filled by cation
HCP anion, all octahedral holes filled by cation
CCP anion, all one type of tetrahedral holes (i.e. half) filled by cation
HCP anion, all one type of tetrahedral holes (i.e. half) filled by cation
CCP anion, all one type of tetrahedral holes (i.e. half) filled by cation
CCP cation, all one type of tetrahedral holes (i.e. half) filled by anion
CCP anion, all octahedral and tetrahedral holes filled by cation
Packing and hole fillingIonic StructureKey Example & Cation:Anion coordination
CCP anion, alternate layers of octahedral holes filled full or empty (i.e. half) by cation
HCP anion, alternate layers of octahedral holes filled full or empty (i.e. half) by cation
CCP anion, half octahedral holes filled in ordered framework by cation
HCP anion, half octahedral holes filled in ordered framework by cation
CCP anion, alternate layers of octahedral holes filled 2/3 full or empty (i.e. 1/3) by cation
HCP anion, alternate layers of octahedral holes filled 2/3 full or empty (i.e. 1/3) by cation
Primitive cubic arrangement of anion, cation on all edges
Primitive cubic arrangement of small cation, oxygen on edges and larger cation in centre
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Last Updated: Feb 16, 2017

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