| Movie | Villain | Actor |
| 1. Psycho (1960) | |
| 2. The Silence of the Lambs (1991) | |
| 3. Star Wars Episode IV: A New Hope (1977) | |
| 4. One Flew Over the Cuckoo's Nest (1975) | |
| 5. Schindler's List (1993) | |
| 6. 2001: A Space Odyssey (1968) | |
| 7. M (1931) | |
| 8. It's a Wonderful Life (1946) | |
| 9. The Exorcist (1973) | |
| 10. Snow White and the Seven Dwarfs (1937) | |
| 11. The Godfather II (1974) | |
| 12. The Wizard of Oz (1939) | |
| 13. No Country for Old Men (2007) | |
| 14. A Clockwork Orange (1971) | |
| 15. Misery (1990) | |
| 16. The Dark Knight (2008) | |
| 17. You Only Live Twice (1967) | |
| 18. Fatal Attraction (1987) | |
| 19. Mutiny on the Bounty (1935) | |
| 20. Double Indemnity (1944) | |
| 21. Cape Fear (1962) | |
| 22. The Machurian Candidate (1962) | |
| 23. A Nightmare on Elm Street (1984) | |
| 24. All About Eve (1950) | |
| 25. The Terminator (1984) | |
| 26. Chinatown (1974) | |
| 27. The Shining (1980) | |
| 28. White Heat (1949) | |
| 29. Wall Street (1987) | |
| 30. Sleeping Beauty (1959) | |
| 31. City of God (2002) | |
| 32. The Night of the Hunter (1955) | |
| 33. Rebecca (1940) | |
| 34. Star Wars Episode III: Revenge of the Sith (2005) | |