Which came first?

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Can you name the following that were the first of their kind??

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Who/What was/is the first...
Colour Best Picture winner?
Soviet Republic to break away from the USSR?
Talkie movie?
Independent nation in Latin America?
Superbowl winning quarterback?
Video Game system to have online access?
Reality show to top the Neilsen ratings for a year?
US Vice President?
African American US President?
UN Secretary General?
Video played on MTV?
Holy Roman Emperor?
African American Oscar winner?
Who/What was/is the first...
Newton's Laws of Motion?
Album to sell more than 50 Million copies?
Movie to gross over $1 billion?
Tudor King of England?
50 Goal Scorer in a Season (NHL)?
Element on the Periodic Table?
Cy Young winner?
Host of SNL?
Word in standard dictionaries?
Book of the New Testament?
American Nobel Prize in Literature?
Country to give women the right to vote?

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