Which came first?

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Can you name the following that were the first of their kind??

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Who/What was/is the first...
Book of the New Testament?
50 Goal Scorer in a Season (NHL)?
Newton's Laws of Motion?
Host of SNL?
Soviet Republic to break away from the USSR?
African American Oscar winner?
Element on the Periodic Table?
Album to sell more than 50 Million copies?
US Vice President?
Video Game system to have online access?
Country to give women the right to vote?
Movie to gross over $1 billion?
Talkie movie?
Who/What was/is the first...
UN Secretary General?
Independent nation in Latin America?
American Nobel Prize in Literature?
Colour Best Picture winner?
Tudor King of England?
Video played on MTV?
Superbowl winning quarterback?
Reality show to top the Neilsen ratings for a year?
Holy Roman Emperor?
African American US President?
Word in standard dictionaries?
Cy Young winner?

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