Miscellaneous / Which came first?

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Can you name the following that were the first of their kind??

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Who/What was/is the first...
African American Oscar winner?
Newton's Laws of Motion?
50 Goal Scorer in a Season (NHL)?
American Nobel Prize in Literature?
Colour Best Picture winner?
Word in standard dictionaries?
Country to give women the right to vote?
Superbowl winning quarterback?
Talkie movie?
Holy Roman Emperor?
African American US President?
Element on the Periodic Table?
Reality show to top the Neilsen ratings for a year?
Who/What was/is the first...
Video Game system to have online access?
US Vice President?
Movie to gross over $1 billion?
Cy Young winner?
Book of the New Testament?
Soviet Republic to break away from the USSR?
Tudor King of England?
Album to sell more than 50 Million copies?
Independent nation in Latin America?
Host of SNL?
Video played on MTV?
UN Secretary General?

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