Which came first?

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Can you name the following that were the first of their kind??

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Who/What was/is the first...
Host of SNL?
African American Oscar winner?
Talkie movie?
Book of the New Testament?
Colour Best Picture winner?
Holy Roman Emperor?
Cy Young winner?
Reality show to top the Neilsen ratings for a year?
Soviet Republic to break away from the USSR?
Tudor King of England?
American Nobel Prize in Literature?
Word in standard dictionaries?
African American US President?
Who/What was/is the first...
Superbowl winning quarterback?
Newton's Laws of Motion?
Video played on MTV?
50 Goal Scorer in a Season (NHL)?
UN Secretary General?
Movie to gross over $1 billion?
Element on the Periodic Table?
US Vice President?
Country to give women the right to vote?
Video Game system to have online access?
Album to sell more than 50 Million copies?
Independent nation in Latin America?

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