Miscellaneous / Which came first?

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Can you name the following that were the first of their kind??

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Who/What was/is the first...
UN Secretary General?
Movie to gross over $1 billion?
Cy Young winner?
Country to give women the right to vote?
Album to sell more than 50 Million copies?
African American US President?
Soviet Republic to break away from the USSR?
Reality show to top the Neilsen ratings for a year?
American Nobel Prize in Literature?
Book of the New Testament?
Tudor King of England?
Video played on MTV?
Newton's Laws of Motion?
Who/What was/is the first...
Holy Roman Emperor?
Independent nation in Latin America?
Superbowl winning quarterback?
Word in standard dictionaries?
Host of SNL?
Talkie movie?
US Vice President?
Colour Best Picture winner?
Video Game system to have online access?
50 Goal Scorer in a Season (NHL)?
Element on the Periodic Table?
African American Oscar winner?

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