Which came first?

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Can you name the following that were the first of their kind??

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Who/What was/is the first...
American Nobel Prize in Literature?
Soviet Republic to break away from the USSR?
Word in standard dictionaries?
Independent nation in Latin America?
Video Game system to have online access?
Tudor King of England?
Element on the Periodic Table?
Book of the New Testament?
Superbowl winning quarterback?
Newton's Laws of Motion?
Host of SNL?
Movie to gross over $1 billion?
UN Secretary General?
Who/What was/is the first...
African American US President?
Holy Roman Emperor?
Colour Best Picture winner?
Album to sell more than 50 Million copies?
Video played on MTV?
African American Oscar winner?
Cy Young winner?
Country to give women the right to vote?
Reality show to top the Neilsen ratings for a year?
50 Goal Scorer in a Season (NHL)?
Talkie movie?
US Vice President?

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