Which came first?

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Can you name the following that were the first of their kind??

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Who/What was/is the first...
Album to sell more than 50 Million copies?
Talkie movie?
Independent nation in Latin America?
African American Oscar winner?
Tudor King of England?
50 Goal Scorer in a Season (NHL)?
Movie to gross over $1 billion?
Holy Roman Emperor?
Word in standard dictionaries?
Host of SNL?
Colour Best Picture winner?
UN Secretary General?
American Nobel Prize in Literature?
Who/What was/is the first...
Element on the Periodic Table?
Superbowl winning quarterback?
Reality show to top the Neilsen ratings for a year?
African American US President?
Video played on MTV?
Cy Young winner?
Country to give women the right to vote?
US Vice President?
Video Game system to have online access?
Soviet Republic to break away from the USSR?
Book of the New Testament?
Newton's Laws of Motion?

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