Which came first?

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Can you name the following that were the first of their kind??

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Who/What was/is the first...
Video Game system to have online access?
American Nobel Prize in Literature?
UN Secretary General?
Video played on MTV?
Soviet Republic to break away from the USSR?
African American Oscar winner?
Reality show to top the Neilsen ratings for a year?
Element on the Periodic Table?
Holy Roman Emperor?
Country to give women the right to vote?
Host of SNL?
Talkie movie?
Colour Best Picture winner?
Who/What was/is the first...
Word in standard dictionaries?
Tudor King of England?
Independent nation in Latin America?
US Vice President?
Superbowl winning quarterback?
Book of the New Testament?
Album to sell more than 50 Million copies?
Newton's Laws of Motion?
Movie to gross over $1 billion?
African American US President?
Cy Young winner?
50 Goal Scorer in a Season (NHL)?

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