Which came first?

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Can you name the following that were the first of their kind??

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Who/What was/is the first...
50 Goal Scorer in a Season (NHL)?
Colour Best Picture winner?
Word in standard dictionaries?
American Nobel Prize in Literature?
Video Game system to have online access?
Reality show to top the Neilsen ratings for a year?
UN Secretary General?
Cy Young winner?
Movie to gross over $1 billion?
Country to give women the right to vote?
Album to sell more than 50 Million copies?
Talkie movie?
Host of SNL?
Who/What was/is the first...
African American US President?
Newton's Laws of Motion?
Video played on MTV?
Superbowl winning quarterback?
Tudor King of England?
Independent nation in Latin America?
African American Oscar winner?
Soviet Republic to break away from the USSR?
Book of the New Testament?
US Vice President?
Element on the Periodic Table?
Holy Roman Emperor?

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