Match the Superhero to their Villain

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Can you name the Match the Superhero to their Villain?

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VillainSuperhero/es
The Unicorn
Mister Fear
Zzzax
Doctor Faustus
Sauron
Big Wheel
Tattooed Man
Minister Blizzard
VillainSuperhero/es
Terra-Man
The Orb
Rainbow Raider
Constantine Drakon
Jigsaw
Puppet Master
The Great White Shark
Shadow Thief

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