| Serial | Villain |
| Robot | |
| Robot | |
| Robot | |
| The Ark in Space | |
| The Sontaran Experiment | |
| Genesis of the (villains) | |
| Genesis of the (villains) | |
| Genesis of the (villains) | |
| Revenge of the (villains) | |
| Revenge of the (villains) | |
| Revenge of the (villains) | |
| Terror of the (villains) | |
| Terror of the (villains) | |
| Planet of Evil | |
| Pyramids of Mars | |
| Pyramids of Mars | |
| The Android Invasion | |
| The Brain of (villain) | |
| The Brain of (villain) | |
| The Seeds of Doom | |
| The Seeds of Doom | |
| The Masque of Mandragora | |
| The Masque of Mandragora | |
| The Masque of Mandragora | |
| The Hand of Fear | |
| The Deadly Assassin | |
| The Deadly Assassin | |
| | Serial | Villain |
| The Face of Evil | |
| The Robots of Death | |
| The Talons of Weng-Chiang | |
| The Talons of Weng-Chiang | |
| The Talons of Weng-Chiang | |
| Horror of Fang Rock | |
| The Invisible Enemy | |
| Image of the Fendahl | |
| Image of the Fendahl | |
| The Sun Makers | |
| The Sun Makers | |
| Underworld | |
| Underworld | |
| The Invasion of Time | |
| The Invasion of Time | |
| The Invasion of Time | |
| The Ribos Operation | |
| The Pirate Planet | |
| The Pirate Planet | |
| The Stones of Blood | |
| The Stones of Blood | |
| The Androids of Tara | |
| The Power of (villain) | |
| The Power of (villain) | |
| The Power of (villain) | |
| The Armageddon Factor | |
| The Armageddon Factor | |
| | Serial | Villain |
| The Armageddon Factor | |
| The Armageddon Factor | |
| Destiny of the (villains) | |
| Destiny of the (villains) | |
| Destiny of the (villains) | |
| City of Death | |
| The Creature from the Pit | |
| Nightmare of Eden | |
| Nightmare of Eden | |
| The Horns of (villain) | |
| The Horns of (villain) | |
| Shada | |
| Shada | |
| The Leisure Hive | |
| The Leisure Hive | |
| Meglos | |
| Meglos | |
| Full Circle | |
| State of Decay | |
| State of Decay | |
| State of Decay | |
| State of Decay | |
| Warrior's Gate | |
| Warrior's Gate | |
| The Keeper of Traken | |
| Logopolis | |
| Sontarans | |
| Robot | |
| The Ark in Space | |
| The Sontaran Experiment | |
| Genesis of the Daleks | |
| Revenge of the Cybermen | |
| Pyramids of Mars | |
| Pyramids of Mars | |
| The Android Invasion | |
| The Android Invasion | |
| The Android Invasion | |
| The Seeds of Doom | |
| The Face of Evil | |
| The Robots of Death | |
| The Stones of Blood | |
| The Androids of Tara | |
| The Power of Kroll | |
| City of Death | |
| The Creature from the Pit | |
| The Creature from the Pit | |
| The Creature from the Pit | |
| Meglos | |
|