Organic Chemistry Chapter 14,17,18

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Question/DefinitionReagentExtra Info
Breaking an Ether
Alkene to Epoxide
Opening an Epoxide X group, 1 step
Opening an EpoxideCN group
Benzene1,3
BenzeneReduction
Thiol to Sulfide
Crown Ether that Solvates Sodium
Disulfide to Thiols
Adding a R Group to a SulfidePlaces positive charge on Sulfur atom. Great alkylating agent
Benzene1,4
Allylic Alcohol to EpoxideEpoxide on top, after orienting correctly
Opening an EpoxideOH group 1 step
Crown Ether that Solvates Potassium
BenzeneNH2 group
Allylic Alcohol to EpoxideEpoxide on bottom, after orienting correctly
BenzeneKetone group
Alkyl Halide to ThiolInversion of configuration
Alkene addition of RO group Markovnikov, no carbocation rearrangement
Question/DefinitionReagentExtra Info
Williamson Ether Synthesis Starts with R-OH. Beware steric hinderance.
Opening an EpoxideRO group 2 steps
BenzeneCarboxylic acid group
Opening an EpoxideRO group 1 step
BenzeneEthyne
Opening an EpoxideSH group, 1 step
Crown Ether that Solvates Lithium
BenzeneOCH3 group
Opening an EpoxideSH group
BenzeneOH group
BenzeneCH3 group
Sulfide to Sulfoxide
Opening an EpoxideOH group 2 steps
Opening an EpoxideR group
Sulfide to Sulfone
Benzene1,2
Thiols to Disulfide
Opening an EpoxideH group
BenzeneAldehyde group

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